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To help find the exact file you need, could you specify your (PPSSPP Emulator or real PSP hardware)? If you know the game region (EU or US), let me know so I can guide you to the correct version.
If you need help setting this up, let me know you are playing on (original PSP or PPSSPP emulator) and which region your game is from so I can guide you through the exact steps. Share public link pes 5 psp save data link